
Organic Mass Spectrometry p. 773 - 776 (1989)
Update date:2022-08-03
Topics:
Rontani, J.-F.
Giusti, G.
The influence of n-butyl group position upon the fragmentation behaviour of the three isomeric n-butylcyclohexanones was studied.The different fragmentation processes are described and have been applied to the differentation of the positional isomers of long-chain n-alkylcyclohexanones.In the case of the 4-n-alkyl isomers, an interesting mechanism involving a recyclization is proposed and substantiated by deuterium labelling.
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