161265-08-3Relevant academic research and scientific papers
A NOVEL DIASTEREOSELECTIVE SYNTHESIS OF CHIRAL, NON-RACEMIC UNSYMMETRICAL THIOACETALS USING SILICON-INDUCED PUMMERER-TYPE REACTION
Shibata, Norio,Fujita, Shigekazu,Gyoten, Michiyo,Matsumoto, Keita,Kita, Yasuyuki
, p. 109 - 112 (1995)
Chiral, non-racemic sulfoxides were reacted with thiols and BSA in the presence of a catalytic amount of TMSOTf in MeCN at rt overnight to give the corresponding chiral, non-racemic anti-thioacetals with high diastereoselectivity.
