A NOVEL DIASTEREOSELECTIVE SYNTHESIS OF CHIRAL, NON-RACEMIC UNSYMMETRICAL THIOACETALS USING SILICON-INDUCED PUMMERER-TYPE REACTION

DOI: 10.1016/0040-4039(94)02178-E

Source and publish data:

Tetrahedron Letters p. 109 - 112 (1995)

Update date:2022-09-26

Topics:

Authors:

Shibata, Norio

Fujita, Shigekazu

Gyoten, Michiyo

Matsumoto, Keita

Kita, Yasuyuki

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Article abstract of DOI:10.1016/0040-4039(94)02178-E

Chiral, non-racemic sulfoxides were reacted with thiols and BSA in the presence of a catalytic amount of TMSOTf in MeCN at rt overnight to give the corresponding chiral, non-racemic anti-thioacetals with high diastereoselectivity.

Full text of DOI:10.1016/0040-4039(94)02178-E

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