161265-32-3Relevant articles and documents
Palladium-catalyzed cross-coupling reaction of organostannoates with aryl halides in aqueous medium
Roshchin, Alexander I.,Bumagin, Nikolai A.,Beletskaya, Irina P.
, p. 125 - 128 (1995)
Water-soluble hydroxycomplexes 2, easily formed from organotin trihalides 1 in aqueous alkaline solution, react readily with aryl halides in the same medium in the presence of palladium complexes to give cross-coupled products 3 in high yields.
1,5,7-triazabicyclo[4.4.0]dec-1-ene-mediated acetylene dicarboxylation and alkyne carboxylation using carbon dioxide
Wang, Xi,Lim, Yu Na,Lee, Chan,Jang, Hye-Young,Lee, Bun Yeoul
supporting information, p. 1867 - 1871 (2013/04/24)
Direct carboxylation of acetylene with CO2 was carried out in the presence of 1,5,7-triazabicyclo[4.4.0]dec-1-ene (TBD); subsequent reduction of dicarboxylated acetylene produces commercially valuable succinate salts. This metal-free carboxylation has potential economic and environmental impact by utilizing non-petroleum feedstocks (acetylene) and CO2 and by producing valuable chemical feed stocks. Direct carboxylation of acetylene with CO2 was carried out in the presence of 1,5,7-triazabicyclo[4.4.0]dec- 1-ene (TBD); subsequent reduction of dicarboxylated acetylene produces commercially valuable succinate salts. This metal-free carboxylation has potential economic and environmental impact by utilizing non-petroleum feedstocks (acetylene) and CO2 and by producing valuable chemical feed stocks.
Palladium-catalyzed cross coupling of organohalostannanes with aryl halides in aqueous medium
Bumagin,Roshchin
, p. 57 - 63 (2007/10/03)
The water-soluble hydroxo complexes formed from organotrihalostannanes in aqueous alkali readily react in the presence of palladium in the same medium with aryl halides to give cross-coupling products in high yields.
