1612874-06-2

Basic information

• Product Name: [Mn(2,2’-bipyridine)₃]⁺[(CO)₃Mn(μ-phenylsulfide)₃Mn(CO)₃]^-
• CAS NO: 1612874-06-2
• Molecular Weight: 1128.95
• Mol File: 1612874-06-2.mol

Chemical Properties

• CAS DataBase Reference: [Mn(2,2’-bipyridine)₃]⁺[(CO)₃Mn(μ-phenylsulfide)₃Mn(CO)₃]^-(CAS DataBase Reference)
• NIST Chemistry Reference: [Mn(2,2’-bipyridine)₃]⁺[(CO)₃Mn(μ-phenylsulfide)₃Mn(CO)₃]^-(1612874-06-2)
• EPA Substance Registry System: [Mn(2,2’-bipyridine)₃]⁺[(CO)₃Mn(μ-phenylsulfide)₃Mn(CO)₃]^-(1612874-06-2)

Safety Data

• Hazardous Substances Data: 1612874-06-2(Hazardous Substances Data)

Upstream product

• 366-18-7 [2,2]bipyridinyl 
• 21240-14-2 [Mn(CO)₄(μ-phenylsulfide)]₂ 
• 10170-69-1 dimanganese decacarbonyl 
• 882-33-7 diphenyldisulfane 

Relevant articles and documents

Electrocatalytic hydrogen generation by a trithiolato-bridged dimanganese hexacarbonyl anion with a turnover frequency exceeding 40000 s-1

An unusual ionic manganese model complex [Mn(bpy)3] +[(CO)3Mn(μ-SPh)3Mn(CO)3] -(bpy: 2,2′-bipyridine) has been synthesized, which bears some structural resemblance to the active site of [FeFe] hydrogenase. An overpotential of 0.61 V has been determined for the electrocatalytic proton reduction using this complex in CH3CN with CF3COOH as the proton source. A turnover frequency of 44600 s-1 is achieved at high scan rates and in the presence of a large amount of acid. This journal is the Partner Organisations 2014.