1612875-45-2Relevant academic research and scientific papers
C-H activation at a bidentate ligand coordinated to palladium(II) - An electrophilic attack supported by an external base
Cayir, Merve,Ghoochany, Leila Taghizadeh,Walli, Adam,Busch, Mark,Sun, Yu,Meyer, Franc,Br?se, Stefan,Thiel, Werner R.
, p. 2618 - 2624 (2014)
2-(2-Phenylaminopyrimidin-4-yl)pyridines undergo C-H activation at the phenyl ring in the ortho position to the amine nitrogen atom when reacted with (PhCN)2PdCl2 and finally form N,N,C-coordinated palladium(II) complexes in high yields. Five differently substituted complexes were synthesized and characterized by spectroscopy and X-ray structure analysis. The reaction mechanism for the formation of these complexes was elucidated by kinetic experiments, which allowed the calculation of the activation parameters of the complex formation.
C-H activation at a bidentate ligand coordinated to palladium(II) - An electrophilic attack supported by an external base
Cayir, Merve,Ghoochany, Leila Taghizadeh,Walli, Adam,Busch, Mark,Sun, Yu,Meyer, Franc,Br?se, Stefan,Thiel, Werner R.
, p. 2618 - 2624 (2015/04/27)
2-(2-Phenylaminopyrimidin-4-yl)pyridines undergo C-H activation at the phenyl ring in the ortho position to the amine nitrogen atom when reacted with (PhCN)2PdCl2 and finally form N,N,C-coordinated palladium(II) complexes in high yields. Five differently substituted complexes were synthesized and characterized by spectroscopy and X-ray structure analysis. The reaction mechanism for the formation of these complexes was elucidated by kinetic experiments, which allowed the calculation of the activation parameters of the complex formation.
