1613059-57-6Relevant articles and documents
N,N-Dimethylaminobenzoates enable highly enantioselective Sharpless dihydroxylations of 1,1-disubstituted alkenes
Zhao, Yaohong,Xing, Xiangyou,Zhang, Shaolong,Wang, David Zhigang
supporting information, p. 4314 - 4317 (2014/06/23)
A design scenario aimed at exploring beneficial catalyst-substrate π-π stacking electronic interactions in the classical Sharpless asymmetric dihydroxylations (SAD) leads to the identification of highly polarizable allylic N,N-dimethylaminobenzoate as a remarkably efficient auxiliary for inducing high levels of enantioselectivities (up to 99% ee) in the traditionally challenging substrate class of 1,1-disubstituted aliphatic alkenes. the Partner Organisations 2014.