1613289-94-3Relevant articles and documents
Selective C(sp3)-H activation of simple alkanes: visible light-induced metal-free synthesis of phenanthridines with H2O2as a sustainable oxidant
Duan, Chunying,Jin, Yunhe,Meng, Changgong,Wang, Lifang,Zhang, Qingqing,Zhang, Yongqiang
supporting information, p. 6926 - 6930 (2021/09/28)
The visible light-induced metal-free C(sp3)-H phenanthridinylation of simple alkanes with isonitrile is developed with H2O2as a terminal green oxidant. This reaction features good yields and selectivities, mild conditions, and a broad substrate scope with gaseous alkanes involved, allowing practical access to valuable alkyl-substituted phenanthridine derivatives.
Transformations of Isonitriles with Bromoalkanes Using Photoredox Gold Catalysis
Rohe, Samantha,McCallum, Terry,Morris, Avery O.,Barriault, Louis
, p. 10015 - 10024 (2018/07/21)
Isonitriles have excellent electronic compatibility to react with free radicals. Recently, photoredox catalysis has emerged as a powerful tool for the construction of C-C bonds with few protocols for alkylative heterocycle synthesis through isonitrile addition. Herein, we describe the photocatalytic generation of alkyl radicals from unactivated bromoalkanes as part of an efficient cross-coupling strategy for the diversification of isonitriles using a dimeric gold(I) photoredox catalyst, [Au2(dppm)2]Cl2.
