161330-98-9Relevant academic research and scientific papers
The [2,3] sigmatropic rearrangement of N-benzyl-O-allylhydroxylamines
Davies, Stephen G.,Fox, John F.,Jones, Simon,Price, Anne J.,Sanz, Miguel A.,Sellers, Thomas G. R.,Smith, Andrew D.,Teixeira, Fatima C.
, p. 1757 - 1765 (2007/10/03)
The rearrangement of a range of N-benzyl-O-allylhydroxylamines to the corresponding N-allylhydroxylamines upon treatment with n-BuLi in THF, followed by reduction to the corresponding N-allylamines, is described. Mechanistic studies of the transformation are consistent with an intramolecular [2,3] sigmatropic rearrangement.
A novel [2,3] intramolecular rearrangement of N-benzyl-O-allylhydroxylamines
Davies, Stephen G.,Jones, Simon,Sanz, Miguel A.,Teixeira, Fatima C.,Fox, John F.
, p. 2235 - 2236 (2007/10/03)
A novel [2,3]-sigmatropic rearrangement whereby N-benzyl-O-allylhydroxylamines undergo transformation to the corresponding N-allylhydroxylamines, which can subsequently be reduced to the corresponding allylamines, is described and evidence for the intramolecular nature of this process presented.
New Synthesis of Isoxazolidines from the Selenium-Induced Cyclization of O-Allyl Hydroxylamines
Tiecco, Marcello,Testaferri, Lorenzo,Tingoli, Marco,Santi, Claudio
, p. 163 - 166 (2007/10/02)
The reaction of O-allyl hydroxylamines with phenylselenenyl sulfate, generated from the oxidation of diphenyl diselenide with ammonium persulfate, easily affords N-alkyl isoxazolidines as the result of a cyclization reaction through the formation of a car
