1613403-63-6Relevant academic research and scientific papers
Stereoselective synthesis of conjugated trienes: Via 1,4-palladium migration/Heck sequence
Feng, Chen-Guo,He, Zhi-Tao,Li, Meng-Yao,Lin, Guo-Qiang,Xue, Ze-Jian,Zhu, Bin-Bin
, p. 14420 - 14422 (2020)
Conjugated trienes are ubiquitous structures in natural products and organic functional molecules. An efficient 1,4-palladium migration/Heck sequence was developed for the highly stereoselective synthesis of trisubstituent 1,3,5-trienes, which were found
Palladium(II)/Lewis acid synergistically catalyzed allylic C-H olefination
Wang, Pu-Sheng,Lin, Hua-Chen,Zhou, Xiao-Le,Gong, Liu-Zhu
, p. 3332 - 3335 (2014/07/08)
The first allylic C-H olefination with α-diazo esters synergistically catalyzed by a palladium(II) complex and (salen)CrCl has been established to directly generate conjugated polyene derivatives in moderate to high yields and with excellent stereoselectivities.
