16136-73-5

Upstream product

• 67-56-1 methanol 
• 16713-89-6 O¹,O²-isopropylidene-O³-(toluene-4-sulfonyl)-5-deoxy-α-D-xylofuranose 
• 29873-56-1 5-deoxy-5-iodo-1,2-O-isopropylidene-3-O-p-tolylsulfonyl-α-D-xylofuranose 
• 4152-79-8 1,2-O-isopropylidene-5-methyl-5-deoxy-α-D-xylofuranose 
• 98-59-9 p-toluenesulfonyl chloride 
• 68660-56-0 1,2-di-O-acetyl-5-deoxy-3-O-p-tolylsulfonyl-D-xylofuranose 

Downstream Products

• 93215-29-3 methyl-2,5-didesoxy-2-C-methyl-3-O-benzyl-α-D-arabinofuranoside 
• 93215-32-8 3-O-benzyl-2,5-dideoxy-2-C-methyl-β-D-arabinofuranose 
• 93215-31-7 3-O-benzyl-2,5-dideoxy-2-C-methyl-α-D-arabinofuranose 

Relevant academic research and scientific papers

Enzymic hydrolysis of methyl 2,3-di-O-acetyl-5-deoxy-α and β-D-xylofuranosides - An active-site model of pig liver esterase

The regioselective enzymic hydrolysis of methyl 2,3-di-O-acetyl-5-deoxy-α-D-xylofuranoside (1) and methyl 2,3-di-O-acetyl-5-deoxy-β-D-xylofuranoside (2) in the presence of pig liver esterase (PLE) was studied by GLC. Diacetate 2 gave exclusively methyl 3-

SYNTHESIS OF 2,5-DIDEOXY-2-C-METHYL-D-ARABINOSE DERIVATIVES FROM METHYL 2,3-ANHYDRO-5-DEOXY-α-D-RIBOFURANOSIDE

Treatment of methyl 2,3-anhydro-5-deoxy-α-D-ribofuranoside with lithium dimethyl cuprate gave methyl 2,5-dideoxy-2-C-methyl-α-D-arabinofuranoside (54 percent) and methyl 3,5-dideoxy-3-C-methyl-α-D-xylofuranoside (10 percent).The former was converted into