161365-47-5Relevant academic research and scientific papers
The Synthesis of 7-Carbonyl Homologues of 1-Deoxynojirimycin
Kilonda, Amuri,Compernolle, Frans,Toppet, Suzanne,Hoornaert, Georges J.
, p. 9047 - 9050 (1994)
A 3,4;5,6-di-O-isopropylidene salt derivative of 1-amino-1-deoxy-D-glucitol was transformed to N-Boc protected (5,6)-α,β-unsaturated 7-carbonyl compounds.Conversion to the title piperidine products proceeded via deprotection and intramolecular 1,4-additio
The synthesis of ester and ketone analogues of 1-deoxynojirimycin and castanospermine
Compernolle, Frans,Joly, Gert,Peeters, Koen,Toppet, Suzanne,Hoornaert, Georges,Kilonda, Amuri,Babady-Bila
, p. 12739 - 12754 (2007/10/03)
1-Amino-1-deoxy-D-glucitol (3) was converted into the 3,4;5,6-di-O-isopropylidene protected ammonium salt 17 which was transformed further into the trans-fused piperidine acetonides 4-8 in six steps and 23-32% overall yield. In the final step, ring closur
