161435-86-5Relevant academic research and scientific papers
Hybrid phosphorus and sulfur donor ligands. Bridged thiolato complexes
Liu, Shiuh-Tzung,Hou, Duen-Ren,Lin, Tu-Chen,Cheng, Ming-Chu,Peng, Shie-Ming
, p. 1529 - 1532 (2008/10/09)
Reaction of o-C6H4(PPhH)(SH) (3) with Mn(CO)5Br and Re(CO)5Br in chloroform provided sulfido-bridged binuclear complexes {fac-[o-C6H4(PPhCl)(μ2-S)]Mn(CO) 3}2 (4) and [o-C6H4(PPhH)(μ2-S)](μ 2-Br)Re2(CO)7 (5), respectively. Both complexes 4 and 5 were characterized by spectral and crystal structural analyses. The hydrogen atom of the secondary phosphine moiety (P-H) of 3 was replaced by a chlorine atom in dimanganese complex 4 to form P-Cl but was retained in rhenium complex 5. Methanolysis of 4 gave methoxyl-substituted product {fac-[o-C6H4(PPh(OCH3))(μ 2-S)]Mn(CO)3}2.
