161466-46-2

Upstream product

• 768-33-2 phenyldimethylsilyl chloride 
• 148933-93-1 <1aR-<1aα,2β,4β,4aα,5α(4R*,6S*),6α>>-5-<2-<6-<2-<<(1,1-Dimethylethyl)diphenylsilyl>oxy>ethyl>-2,2-dimethyl-1,3-dioxan-4-yl>ethyl>-1a,2,4,4a,5,6-hexahydro-2,6-dimethyl-3H-naphth<1,8a-b>oxiren-4-ol 
• 3839-31-4 dimethyl(phenyl)silyllithium 
• 148933-92-0 <1S-<1α(3R*,5S*),2α,6β,8β,8aα>>-1<<(1,1-Dimethyethyl)diphenylsilyl>oxy>-7-(1,2,6,7,8,8a-hexahydro-8-hydroxy-2,6-dimethyl-1-naphthalenyl)-3,5-heptanediol 
• 148969-22-6 <1S-<1α(3R*,5S*),2α,6β,8β,8aα>>-7-(1,2,6,7,8,8a-Hexahydro-8-hydroxy-2,6-dimethyl-1-naphthalenyl)-1,3,5-heptanetriol 
• 75330-75-5 lovastatin 
• 116996-45-3 <1S-<1α,3α,7β,8β(4S^*,6R^*),8aβ>>-8-<2-<6-<2-<<(1,1-dimethylethyl)diphenylsilyl>oxy>ethyl>-2,2-dimethyl-1,3-dioxan-4-yl>ethyl>-1,2,3,7,8,8a-hexahydro-3,7-dimethyl-1-naphthalenol 

Downstream Products

• 116996-32-8 <4R-<4α(4R^*,5R^*),6α>>-5-<2-<6-<2-<<(1,1-dimethylethyl)diphenylsilyl>oxy>ethyl>-2,2-dimethyl-1,3-dioxan-4-yl>ethyl>-4-methyl-2-cyclohexen-1-one 

Relevant academic research and scientific papers

Addition of dimethylphenylsilyl cuprates to vinyl epoxides: Effect of cuprate stoichiometry on stereochemistry and regiochemistry

The stereochemical and regiochemical outcome of reactions of PhMe2SiLi/CuCN mixtures with vinyl epoxides depends on the PhMe2SiLi/CuCN ratio.Keywords: Silicon; Copper; Lithium; Cuprate; Vinyl epoxide; Stereochemistry

Studies on the Degradation of Mevinolin and Compactin: A Formal Route to Semisynthetic Analogues

Procedures are described for degrading mevinolin (1a) and compactin (1b) into the enone 2, which is a substance that has been elaborated into 1a, 1b, and 3-ethylcompactin (1c).Consequently, 2 serves as an advanced intermediate for the construction of semi