161561-87-1

Upstream product

• 622-30-0 N-benzyl hydroxylalmine 
• 161561-86-0 (S)-6-{[(tert-butyldiphenylsilyl)oxy]methyl}-5,6-dihydro-2H-pyran-2-one 

Downstream Products

• 174711-47-8 (3S,5R)-2-benzyl-5-hydroxymethyl-3-methoxycarbonylmethyl-isoxazolidine 
• 161561-91-7 ((3R,5R)-2-Benzyl-5-methanesulfonyloxymethyl-isoxazolidin-3-yl)-acetic acid methyl ester 
• 161561-92-8 ((3R,5R)-5-Azidomethyl-2-benzyl-isoxazolidin-3-yl)-acetic acid methyl ester 
• 161561-90-6 [(3R,5R)-2-Benzyl-5-(tert-butyl-diphenyl-silanyloxymethyl)-isoxazolidin-3-yl]-acetic acid methyl ester 

Relevant academic research and scientific papers

Stereocontrolled entry to negamycin from D-glucose

Conjugate addition-rearrangement of N-benzylhydroxy-lamine to lactone 6 provides isoxazolidin-5-one 7 which was in turn mesylated at the hydroxy group and subjected to the next skeleton rearrangement to afford 3,5-disubstituted isoxazolidine 10. Standard