Stereocontrolled entry to negamycin from D-glucose

DOI: 10.1016/0040-4039(94)02194-G

Source and publish data:

Tetrahedron Letters p. 135 - 138 (1995)

Update date:2022-07-29

Topics:

Authors:

Socha, Darlusz

Jurczak, Margarita

Chmielewski, Marek

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Article abstract of DOI:10.1016/0040-4039(94)02194-G

Conjugate addition-rearrangement of N-benzylhydroxy-lamine to lactone 6 provides isoxazolidin-5-one 7 which was in turn mesylated at the hydroxy group and subjected to the next skeleton rearrangement to afford 3,5-disubstituted isoxazolidine 10. Standard

Full text of DOI:10.1016/0040-4039(94)02194-G

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