1616781-76-0Relevant articles and documents
Radical phosphinylation of α,α-diaryl allylic alcohols with concomitant 1,2-aryl migration
Chu, Xue-Qiang,Zi, You,Meng, Hua,Xu, Xiao-Ping,Ji, Shun-Jun
supporting information, p. 7642 - 7645 (2014/07/08)
A novel radical phosphinylation of α,α-diaryl allylic alcohols with arylphosphine oxides was described for the direct preparation of α-aryl-β-phosphinylated carbonyl ketones in medium to good yields via 1,2-aryl migration. In this reaction, formation of new C(Ar)-C(sp3) and C(sp3)-P bonds was observed.