1616800-21-5Relevant articles and documents
Iron-catalyzed radical aryldifluoromethylation of activated alkenes to difluoromethylated oxindoles
Wang, Jian-Yong,Zhang, Xin,Bao, Yan,Xu, Yue-Ming,Cheng, Xiu-Fen,Wang, Xi-Sheng
supporting information, p. 5582 - 5585 (2014/07/22)
An iron-catalyzed aryldifluoromethylation of activated alkenes under mild reaction conditions has been developed, which is a rare example where a cosolvent is used to improve the reaction yield along with Fenton's reagent and thus provides an economic and green method for the synthesis of a variety of difluoromethylated oxindoles. Preliminary mechanistic investigations indicate a radical addition path. the Partner Organisations 2014.