1616976-30-7

Basic information

• Product Name: C₁₉H₃₁O₅PSSi
• CAS NO: 1616976-30-7
• Molecular Weight: 430.577
• Mol File: 1616976-30-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₉H₃₁O₅PSSi(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₉H₃₁O₅PSSi(1616976-30-7)
• EPA Substance Registry System: C₁₉H₃₁O₅PSSi(1616976-30-7)

Safety Data

• Hazardous Substances Data: 1616976-30-7(Hazardous Substances Data)

Upstream product

• 60774-64-3 2-(phenylsulfinyl)cycloheptanone 

Relevant articles and documents

The sila-Pummerer reaction of γ-silyl substituted cycloalkanoyl sulfoxides: The first examples and a new approach to 3-substituted cycloalk-2-enones

The thermal decomposition of 3-(α-trimethylsilyl)alkyl substituted 2-(phenylsulfinyl)cycloalkanones occurs via the γ-sila-Pummerer reaction, affording 3-substituted cycloalk-2-enones and unstable trimethylsilyl benzenesulfenate as an elimination by-product. The starting γ-silyl substituted cycloalkanoyl sulfoxides were obtained through the conjugate addition reaction of nucleophilic reagents to 2-(phenylsulfinyl)cycloalk-2- enones. The tandem conjugate addition/γ-sila-Pummerer reaction investigated here provides a new route to 3-substituted cycloalk-2-enones.