60774-64-3

Basic information

• Product Name: 2-(phenylsulfinyl)cycloheptanone
• Synonyms: 2-(phenylsulfinyl)cycloheptanone
• CAS NO: 60774-64-3
• Molecular Weight: 236.335
• Mol File: 60774-64-3.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 2-(phenylsulfinyl)cycloheptanone(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(phenylsulfinyl)cycloheptanone(60774-64-3)
• EPA Substance Registry System: 2-(phenylsulfinyl)cycloheptanone(60774-64-3)

Safety Data

• Hazardous Substances Data: 60774-64-3(Hazardous Substances Data)

Upstream product

• 4972-29-6 benzenesulphinyl chloride 
• 22081-48-7 (cyclohept-1-en-1-yloxy)(trimethyl)silane 
• 52190-41-7 2-phenylsulfanylcycloheptanone 
• 94-36-0 dibenzoyl peroxide 
• 31268-20-9 bromomethyl phenyl sulfoxide 
• 158916-92-8 1-cyclohexanol 
• 21849-27-4 1-(Phenylsulfinylchlormethyl)-cyclohexanol 
• 7205-94-9 chloromethyl phenyl sulfoxide 
• 65325-68-0 1-(monofluoromethyl sulfinyl)benzene 

Downstream Products

• 1616976-30-7 C₁₉H₃₁O₅PSSi 
• 169691-02-5 2-(Phenylsulfonyl)-2-cycloheptenone 
• 169690-99-7 2-(phenylsulfinyl)cyclohept-2-en-1-one 
• 85808-24-8 2-(phenylsulfanyl)-2-cycloheptenone 

Relevant articles and documents

α-Benzoyloxylation of β-keto sulfides at ambient temperature

A facile and efficient protocol for the α-benzoyloxylation of β-keto sulfides is presented. This methodology provides a step-economical, mild and practical access to highly functionalized α-O-benzoyloxy substituted β-keto sulfides, including those with quaternary carbons, which are not easily obtained through currently available methods.

α-Sulfinyl carbenoid: One-carbon homologation of ketones to α-sulfinyl ketones using chloromethyl phenyl sulfoxide

Addition of the carbanion of chloromethyl phenyl sulfoxide to ketones gave the adducts, which were treated with lithium diisopropylamide to afford one-carbon homologated α-sulfinyl ketones via α-sulfinyl carbenoids in moderate to high yields.