1617568-11-2Relevant academic research and scientific papers
Organocatalytic enantioselective allylic alkylation of MBH carbonates with β-keto esters
Kamlar,Hybelbauerova,Cisarova,Vesely
supporting information, p. 5071 - 5076 (2014/07/08)
The highly stereoselective allylic alkylation of Morita-Baylis-Hillman carbonates with β-ketoesters catalysed by β-ICD is described. The corresponding products containing two adjacent quaternary and tertiary carbon centers were obtained in good yields with high diastereoselectivity (up to 10 : 1 dr) and enantioselectivity (up to 95% ee).
