161870-59-3

Upstream product

• 1194813-40-5 1-Hexahydrobenzyl-cyclohexanol-⁽²⁾ 
• 64-19-7 acetic acid 
• 108-94-1 cyclohexanone 
• 62791-22-4 tert-butyl(cyclohex-1-en-1-yloxy)dimethylsilane 
• 1192-37-6 methylenecyclohexane 
• 946-33-8 2-benzylcyclohexan-1-one 
• 2043-61-0 cyclohexanecarbaldehyde 
• 92-83-1 xanthene 
• 24195-40-2 2-(cyclohexylmethylidene)cyclohexanone 
• 90-47-1 xanth-9-one 

Downstream Products

• 6026-77-3 (+/-)-trans-2-Cyclohexylmethyl-cyclohexanol 

Relevant academic research and scientific papers

α-Alkylation of Ketones with Alkenes Enabled by Photoinduced Activation of Silyl Enol Ethers in the Presence of a Small Amount of Water

Under blue-light irradiation conditions with a photocatalyst [1,2,3,5-tetrakis(carbazol-9-yl)-4,6-dicyanobenzene], silyl enol ethers reacted with alkenes in the presence of a small amount of water to afford the α-alkylation products in good to high yields. A thiol cocatalyst was found to expand the substrate scope of the reaction.

Highly Selective Hydrogenation of Aromatic Ketones and Phenols Enabled by Cyclic (Amino)(alkyl)carbene Rhodium Complexes

Air-stable Rh complexes ligated by strongly σ-donating cyclic (amino)(alkyl)carbenes (CAACs) show unique catalytic activity for the selective hydrogenation of aromatic ketones and phenols by reducing the aryl groups. The use of CAAC ligands is essential for achieving high selectivity and conversion. This method is characterized by its good compatibility with unsaturated ketones, esters, carboxylic acids, amides, and amino acids and is scalable without detriment to its efficiency.