161882-45-7Relevant academic research and scientific papers
Asymmetric Diels-Alder reactions of chiral acrylates of cholic acid derivatives
Mathivanan,Maitra
, p. 364 - 369 (2007/10/02)
New steroid-based chiral auxiliaries 6, 9, and 12 have been synthesized from readily available cholic acid. These new chiral auxiliaries place the reactive and the shielding sites in a 1,5 relationship to each other. Diels-Alder reaction of cyclopentadien
Cholic Acid Derived Novel Chiral Auxiliaries for Asymmetric Diels-Alder Reactions
Maitra, Uday,Mathivanan, Packiarajan
, p. 1469 - 1471 (2007/10/02)
Cholic acid-based chiral acrylate 5 yields a Diels-Alder adduct with cyclopentadiene in the presence of BF3*OEt2 with 88 percent diastereoselectivity
