16192-03-3

Basic information

• Product Name: 1-methyl-4-[(2-methylprop-1-en-1-yl)sulfonyl]benzene
• Synonyms: 1-Methyl-4-(2-methyl-1-propenylsulphonyl)-benzene; 1-Methyl-4-[(2-methylprop-1-en-1-yl)sulfonyl]benzene; 4-Methylphenyl 2-methylprop-1-en-1-yl sulfone; benzene, 1-methyl-4-[(2-methyl-1-propen-1-yl)sulfonyl]-
• CAS NO: 16192-03-3
• Molecular Formula: C₁₁H₁₄O₂S
• Molecular Weight: 210.2927
• Mol File: 16192-03-3.mol
• Article Data: 9

Chemical Properties

• Melting Point: 65 °C(Solv: isopropyl ether (108-20-3))
• Boiling Point: 351.6°C at 760 mmHg
• Flash Point: 196.6°C
• Density: 1.104g/cm³
• Vapor Pressure: 8.25E-05mmHg at 25°C
• Refractive Index: 1.525
• CAS DataBase Reference: 1-methyl-4-[(2-methylprop-1-en-1-yl)sulfonyl]benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-methyl-4-[(2-methylprop-1-en-1-yl)sulfonyl]benzene(16192-03-3)
• EPA Substance Registry System: 1-methyl-4-[(2-methylprop-1-en-1-yl)sulfonyl]benzene(16192-03-3)

Safety Data

• Hazardous Substances Data: 16192-03-3(Hazardous Substances Data)

Upstream product

• 3017-69-4 2-methyl-1-propenylbromide 
• 1576-35-8 toluene-4-sulfonic acid hydrazide 
• 1421914-39-7 2-methyl-1-tosylpropan-2-yl acetate 
• 3185-99-7 Methyl p-tolyl sulfone 
• 824-79-3 sodium 4-methylbenzenesulfinate 
• 7257-26-3 sodium p-toluenesulfinate tetrahydrate 
• 5366-49-4 4-toluenesulfonylacetone 
• 110408-63-4 2,2-Dimethyl-propionic acid (Z)-1-methyl-2-(toluene-4-sulfonyl)-vinyl ester 
• 66680-86-2 isobutenyltributyltin 
• 90395-99-6 1-(2-Chloro-2-methyl-propane-1-sulfonyl)-4-methyl-benzene 
• 115-11-7 isobutene 
• 98-59-9 p-toluenesulfonyl chloride 

Downstream Products

• 1344012-78-7 C₂₈H₃₆O₂ 
• 1430110-92-1 (E)-1-methoxy-4-(5-methylhexa-3,5-dien-1-yl)benzene 
• 1430110-95-4 (Z)-1-methoxy-4-(5-methylhexa-3,5-dien-1-yl)benzene 
• 1446691-07-1 C₁₁H₁₃⁽²⁾HO₂S 
• 96667-60-6 2,2-dimethyl-1-(p-tolylsulfonyl)bicyclo<1.1.0>butane 
• 16192-05-5 2-Methyl-2-phenylmercapto-1-<4-tolyl-sulfonyl>-propan 
• 16192-04-4 1-methyl-4-(2-methylallylsulfonyl)benzene 
• 89647-15-4 1-(2-Dodecylsulfanyl-2-methyl-propane-1-sulfonyl)-4-methyl-benzene 
• 89647-16-5 1-(2-Benzylsulfanyl-2-methyl-propane-1-sulfonyl)-4-methyl-benzene 
• 89647-17-6 1-(2-Isopropylsulfanyl-2-methyl-propane-1-sulfonyl)-4-methyl-benzene 
• 104900-81-4 C₂₂H₂₈O₄S₂ 
• 768-49-0 (2-methyl-1-propenyl)-benzene 
• 644-08-6 4-Methylbiphenyl 
• 105962-20-7 1-Methyl-4-(2-methyl-2-phenyl-propane-1-sulfonyl)-benzene 

Relevant articles and documents

Silver-promoted synthesis of vinyl sulfones from vinyl bromides and sulfonyl hydrazides in water

The synthesis of vinyl sulfones via silver-promoted cross-coupling of vinyl bromides with sulfonyl hydrazides was realized. Water was used as the sole solvent. Multisubstituted vinyl sulfones were easily prepared with excellent alkyl group tolerance. A mechanism involving nucleophilic attack of a sulfinate anion was proposed.

New synthesis of allylidenecyclobutanes by the reaction of cyclobutylmagnesium carbenoids with vinyl sulfones

The reaction of cyclobutylmagnesium carbenoids, which were generated from 1-chlorocyclobutyl p-tolyl sulfoxides with EtMgCl via the sulfoxide-magnesium exchange reaction at low temperature, with carbanions derived from vinyl sulfones with n-BuLi or LDA re

Addition-Elomonation Reactions of β-Oxygenated Vinyl Sulphines

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