16193-48-9Relevant academic research and scientific papers
Improved synthesis of C2-symmetrical pyridinediols and synthesis of C(s)-symmetrical pyridinediols
Koning, Bartjan,Buter, Jan,Hulst, Ron,Stroetinga, Roelof,Kellogg, Richard M.
, p. 2735 - 2743 (2000)
Base-induced reaction of 2,6-dimethylpyridine (2,6-lutidine) (1) with two equivalents of various ketones has been reported to provide C2-symmetrical pyridine diols 3. Closer examination reveals that competitive di-addition to a single methyl gr
E-DON-GRUPPIERUNGEN ORGANISCHER VERBINDUNGEN ALS BEVORZUGTE ANGRIFFSSTELLEN FUER NUCLEOPHILE, ALKYLIERENDE UEBERGANGSMETALLREAGENZIEN; EINE ERSTE UEBERSICHT
Kauffmann, Thomas,Abel, Katharina,Bonrath, Werner,Kolb, Martina,Moeller, Thomas,et al.
, p. 5351 - 5354 (1986)
Groupings, consisting of an electrophilic group (keto group, oxirane group) and a neighbouring electron donor group (-OH, -OMe, -NMe2, -2-pyridyl), proved to be especially attractive for various alkylating organotransition metal reagents metal = Ti(4+),
