161955-14-2

Upstream product

• 358-23-6 trifluoromethylsulfonic anhydride 
• 161955-13-1 benzyl 3,6-di-O-pivaloyl-β-D-galactopyranoside 
• 3282-30-2 pivaloyl chloride 
• 4163-60-4 β-D-galactose peracetate 
• 100-51-6 benzyl alcohol 
• 4304-12-5 benzyl β-D-galactopyranoside 
• 10343-13-2 benzyl 2,3,4,6-tetra-O-acetyl-β-D-galactopyranoside 

Downstream Products

• 161955-20-0 benzyl 3,6-di-O-pivaloyl-β-D-mannopyranoside 
• 161955-18-6 benzyl 4-O-acetyl-2-azido-2-deoxy-3,6-di-O-pivaloyl-β-D-mannopyranoside 
• 189693-82-1 benzyl 2,4-bis(O-methoxymethyl)-3,6-di-O-pivaloyl-β-D-mannopyranoside 
• 161955-15-3 benzyl 4-O-acetyl-3,6-di-O-pivaloyl-2-O-(trifluoromethylsulfonyl)-β-D-glucopyranoside 

Relevant academic research and scientific papers

Novel synthetic approaches to manβ1-4GLCNAc and LeX units from N-acetyllactosamine

Regioselective protection of N-acetyllactosamine with triphenylmethyl (trityl) and pivaloyl groups afforded the corresponding 3, 2′, 4′-tri- and 2′,4′-dihydroxyl derivatives in a few steps, respectively; these derivatives were used efficiently for the syntheses of the title compounds from N-acetyllactosamine in 46% (7 steps) and 19% (8 steps) overall yields, respectively.

A novel method for constructing β-D-mannosidic, 2-acetamido-2-deoxy-β-D-mannosidic and 2-deoxy-D-arabino-hexopyranosidic units from the bis(triflate) derivative of β-D-galactoside

An efficient construction of the β-D-mannosidic, 2-acetamido-2-deoxy-β-D-mannosidic, 2-deoxy-2-fluoro-β-D-mannosidic, and 2-deoxy-β-D-arabino-hexopyranosidic units from the same intermediate, 2-4-bis(O-trifluoromethylsulfonyl) derivative of β-D-galactoside, was achieved in good yields in a stepwise inversion at C-4 and C-2 by using cesium acetate, n-Bu4NN3, n-Bu4NF, and n-Bu4NBH4. A convenient and practical protection of β-D-mannoside to the straightforward synthesis of antennary oligosaccharides was also achieved by using cesium trifluoroacetate.

A Novel Method for Constructions of β-D-Mannosidic, 2-Acetamido-2-deoxy-β-D-mannosidic, and 2-Deoxy-β-D-arabino-hexopyranosidic Units from the Bis(triflate) Derivative of β-D-Galactoside

The useful constructions of β-D-mannosidic, 2-acetamido-2-deoxy-β-D-mannosidic, and 2-deoxy-β-D-arabino-hexopyranosidic units from the same intermediate, 2,4-bis(O-trifluoromethanesulfonyl) derivative of β-D-galactoside, were achieved in a stepwise invers