1619901-87-9

Basic information

• Product Name: (2S)-1-(11bS)-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphe pin-4-yl-1,2,3,4-tetrahydro-2-methylquinoline,99%e.e.
• Synonyms: (2S)-1-(11bS)-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphe pin-4-yl-1,2,3,4-tetrahydro-2-methylquinoline,99%e.e.;(2S)-1-(11bS)-(Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl)-2-methyl-1,2,3,4-tetrahydroquinoline;(2S)-1-(11bS)-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphe pin-4-yl-1,2,3,4-tetrahydro-2-methylquinoline
• CAS NO: 1619901-87-9
• Molecular Formula: C30H24NO2P
• Molecular Weight: 461.49
• Mol File: 1619901-87-9.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 654.3±48.0 °C(Predicted)
• Appearance: /
• PKA: 1.35±0.40(Predicted)
• CAS DataBase Reference: (2S)-1-(11bS)-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphe pin-4-yl-1,2,3,4-tetrahydro-2-methylquinoline,99%e.e.(CAS DataBase Reference)
• NIST Chemistry Reference: (2S)-1-(11bS)-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphe pin-4-yl-1,2,3,4-tetrahydro-2-methylquinoline,99%e.e.(1619901-87-9)
• EPA Substance Registry System: (2S)-1-(11bS)-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphe pin-4-yl-1,2,3,4-tetrahydro-2-methylquinoline,99%e.e.(1619901-87-9)

Safety Data

• Hazardous Substances Data: 1619901-87-9(Hazardous Substances Data)

Usage

General Description

The chemical "(2S)-1-(11bS)-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphe pin-4-yl-1,2,3,4-tetrahydro-2-methylquinoline,99%e.e." is a compound with a complex structure, containing a dioxaphosphapin ring attached to a tetrahydro-2-methylquinoline group. It is available in a 99% enantiomeric excess purity, indicating that it predominantly consists of one enantiomer. This chemical may have potential applications in the pharmaceutical or agrochemical industry, as chirality and stereochemistry play crucial roles in determining the biological activity of many compounds. Further research and development may be needed to explore the potential uses of this chemical.

Upstream product

• 18531-99-2 (S)-[1,1']-binaphthalenyl-2,2'-diol 
• 1780-19-4 (R)-1,2,3,4-tetrahydroquinaldine 
• 18531-94-7 (R)-1,1'-Bi-2-naphthol 
• 604-53-5 (R)-(+)-2,2'bis(diphenylphosphino)-1,1'-binaphthalene 

Relevant articles and documents

Palladium-Catalyzed Cascade to Benzoxepins by Using Vinyl-Substituted Donor–Acceptor Cyclopropanes

A palladium-catalyzed intermolecular cascade (4+3) cyclocondensation of salicylaldehydes and vinylcyclopropanes is reported. A key feature of the reaction is the use of a phosphonate group as an acceptor moiety on the cyclopropane, exploiting its propensity to undergo olefination with aldehydes. Subsequent O-allylation enabled the formation of a range of substituted benzoxepinsWith a novel chiral ligand, the products were obtained in generally good yield and with reasonable enantioselectivity.

Iridium-catalyzed allylic alkylation reaction with N-aryl phosphoramidite ligands: Scope and mechanistic studies

A series of N-aryl phosphoramidite ligands has been synthesized and applied to iridium-catalyzed allylic alkylation reactions, offering high regio- and enantioselectivities for a wide variety of substrates. These ligands feature the synthetic convenience and good tolerance of the ortho-substituted cinnamyl carbonates. Mechanistic studies, including DFT calculations and X-ray crystallographic analyses of the (π-allyl)-Ir complexes, reveal that the active iridacycle is formed via C(sp2)-H bond activation.