162005-36-9

Upstream product

• 596-43-0 bromo-triphenyl-methane 
• 162005-34-7 (S)-1-Adamantan-1-yl-ethane-1,2-diol 
• 76-83-5 trityl chloride 
• 2094-73-7 ethyl 1-adamantanecarboxylate 
• 197910-35-3 1-Adamantan-1-yl-ethane-1,2-diol 
• 197910-33-1 Acetic acid adamantan-1-yl-methylsulfanylcarbonyl-methyl ester 
• 19835-38-2 1-adamantylacetyl chloride 
• 31897-94-6 2-(adamantan-1-yl)-N,N-dimethylacetamide 
• 6600-42-6 1-vinyladamantane 

Downstream Products

• 162005-37-0 (-)-1,3-bis<1'-(1-adamantyl)-2'-(triphenylmethyloxyethoxymethyl)>-2,5-dimethoxybenzene 

Relevant academic research and scientific papers

Temperature dependent inversion of enantiomer selectivity in the complexation of optically active azophenolic crown ethers containing alkyl substituents as chiral barriers with chiral amines

Azophenolic crown ethers (S,S)-1, (R,R)-2 and (S,S)-3 have been prepared in enantiomerically pure forms by using (S)-1-(1′-adamantyl)ethane-1,2-diol, (R)-3,3-dimethylbutane-1,2-diol and (S)-propane-1,2-diol, respectively, as chiral subunits, and the assoc

Preparation of Homochiral Crown Ether containing (S)-1-(1-Adamantyl)ethane-1,2-diol as a Chiral Subunit and its Enantioselective Complexation with an Organic Ammonium Cation

Homochiral 1-(1-adamantyl)ethane-1,2-diol (5) was prepared and its absolute configuration was determined to be (S)-(+)-5 by enzymatic and 1H n.m.r. spectroscopic methods.Using (S)-(+)-5 as a chiral subunit, the homochiral crown ether (+)-18 was synthesize