1620080-91-2Relevant academic research and scientific papers
Metal-templated enantioselective enamine/H-bonding dual activation catalysis
Huo, Haohua,Fu, Chen,Wang, Chuanyong,Harms, Klaus,Meggers, Eric
supporting information, p. 10409 - 10411 (2014/09/17)
An octahedral bis-cyclometalated iridium(III) complex catalyzes the enantioselective α-amination of aldehydes with catalyst loadings down to 0.1 mol%. In this metal-templated design, the metal serves as a structural center and provides the exclusive source of chirality, whereas the catalysis is mediated through the organic ligand sphere. This journal is the Partner Organisations 2014.
