1620135-33-2Relevant academic research and scientific papers
Palladium-catalyzed alkenylation of ketone enolates under mild conditions
Grigalunas, Michael,Ankner, Tobias,Norrby, Per-Ola,Wiest, Olaf,Helquist, Paul
, p. 3970 - 3973 (2014)
A protocol for a mild, catalytic, intermolecular alkenylation of ketone enolates has been developed using a Pd/Q-Phos catalyst. Efficient intermolecular coupling of a variety of ketones with alkenyl bromides was achieved with a slight excess of LiHMDS and temperatures down to 0 °C.
