1620519-86-9Relevant academic research and scientific papers
Stereoselective one-pot synthesis of β-alkylsulfide enol esters. Base-triggered rearrangement under mild conditions
Heredia, Adrian A.,Soria-Castro, Silvia M.,Bouchet, Lydia M.,Oksdath-Mansilla, Gabriela,Barrionuevo, Cecilia A.,Caminos, Daniel A.,Bisogno, Fabricio R.,Argueello, Juan E.,Penenory, Alicia B.
, p. 6516 - 6526 (2014/08/18)
A stereoselective one-pot procedure was developed to prepare S-substituted (Z)-enol esters through a base-triggered rearrangement. This transition metal-free multicomponent approach can be performed under an air atmosphere at room temperature, tolerates a wide set of chemical functionalities and generally affords high isolated yields. The (Z)-selectivity arises from the [1,4]-S- to O-acyl migration. the Partner Organisations 2014.
