1620657-23-9Relevant academic research and scientific papers
Silylative cyclopropanation of allyl phosphates with silylboronates
Shintani, Ryo,Fujie, Ryuhei,Takeda, Momotaro,Nozaki, Kyoko
, p. 6546 - 6549 (2014/06/24)
A potassium-bis(trimethylsilyl)amide-mediated cyclopropanation of allyl phosphates with silylboronates has been developed. Unlike the reported copper-catalyzed allylic substitution reactions, the nucleophile selectively attacks at the β-position of the allylic substrates under the present reaction conditions. The mechanism of this process has also been investigated, thus indicating the involvement of a silylpotassium species as the active nucleophilic component.
