1620683-34-2Relevant academic research and scientific papers
Palladium-catalyzed γ-selective arylation of zincated Boc-allylamines
Millet, Anthony,Baudoin, Olivier
supporting information, p. 3998 - 4000 (2014/08/18)
The regio- and diastereoselective arylation of Boc-protected allylamines was performed via a one-pot lithiation/transmetalation to zinc/cross-coupling sequence, through an appropriate choice of a phosphine ligand. A variety of γ-arylated products were obtained in moderate to good yield, and the products could be directly transformed into valuable γ-arylamines and β-aryl aldehydes.
