1620989-71-0

Basic information

• Product Name: C₂₆H₂₆N₂O
• Synonyms: C₂₆H₂₆N₂O
• CAS NO: 1620989-71-0
• Molecular Weight: 382.505
• Mol File: 1620989-71-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₂₆H₂₆N₂O(CAS DataBase Reference)
• NIST Chemistry Reference: C₂₆H₂₆N₂O(1620989-71-0)
• EPA Substance Registry System: C₂₆H₂₆N₂O(1620989-71-0)

Safety Data

• Hazardous Substances Data: 1620989-71-0(Hazardous Substances Data)

Upstream product

• 10002-30-9 S-pyridin-2-yl benzenecarbothioate 
• 167482-98-6 2,2′-((4-(tert-butyl)phenyl)methylene)bis(1H-pyrrole) 
• 939-97-9 4-tert-Butylbenzaldehyde 

Downstream Products

• 1620989-72-1 C₃₀H₃₁N₃ 
• 1620989-86-7 C₄₄H₃₆BN₃O 
• 1620989-77-6 C₃₉H₃₄BN₃O₂ 
• 1620989-76-5 C₃₈H₃₁BN₄O₃ 

Relevant articles and documents

ABC-type meso-triaryl-substituted subporphyrins

ABC-Type subporphyrins 5a-5h, which bear three different meso-aryl substituents, were rationally synthesized by condensation of AB-type tripyrranes and aroyl chlorides. ABC-Type subporphyrins 5i and 5j were synthesized by Pd-catalyzed amination reaction of 4-bromophenyl subporphyrins 5e and 5h, respectively. Comparative studies on these ABC-type subporphyrins with A 3-type subporphyrins and A2B-type subporphyrins revealed that substituent effects are mostly simple superpositions of individual substituents but cooperative effects are recognized for subporphyrins which bear both electron-donating and electron-withdrawing substituents. Despite extensive attempts, enantiomeric separation of B-methoxy ABC-type subporphyrins was unsuccessful, whereas B-phenylated ABC-type subporphyrins were separated to pure enantiomers. Separated enantiomers showed weak but distinct CD signals reflecting the chiral clockwise/anticlockwise arrangements of the meso-aryl substituents. These results suggest facile racemization through S N1-type heterolysis of the B-OMe bond in solution. ABC-Type meso-triaryl-substituted subporphyrins were rationally synthesized. Cooperative substituent effects are noted for donor-acceptor-type subporphyrins. Although the chiral resolution has not been successful for B-methoxy ABC-type subporphyrins, the enantiomers of some B-phenyl subporphyrins have been resolved by using chiral HPLC. Copyright