10002-30-9Relevant articles and documents
Reductive Cleavage of Aromatic Disulfides Using a Polymer-Supported Phosphine Reagent
Amos, Richard A.,Fawcett, Shayne M.
, p. 2637 - 2639 (1984)
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Corey,Clark
, p. 2875,2876 (1979)
S-(2-pyridinyl)-1,1,3,3-tetramethylthiouronium hexafluorophosphate. A new reagent for the synthesis of 2-pyridinethiol esters
Scardovi, Noemi,Garner, Philip P.,Protasiewicz, John D.
, p. 1633 - 1635 (2003)
(Matrix presented) A new thiouronium-based reagent for the synthesis of 2-pyridinethiol esters under non-nucleophilic conditions from the corresponding carboxylic acids was developed. The resulting procedure enables the preparation of previously unavailable α,β-unsaturated 2-pyridinethiol esters as well as their aliphatic and aromatic counterparts.
Cobalt-catalyzed acylation-reactions of (hetero)arylzinc pivalates with thiopyridyl ester derivatives
Lutter, Ferdinand H.,Grokenberger, Lucie,Hofmayer, Maximilian S.,Knochel, Paul
, p. 8241 - 8245 (2019/09/19)
A cobalt-catalyzed acylation reaction of various primary, secondary and tertiary alkyl, benzyl and (hetero)aryl S-pyridyl thioesters with (hetero)arylzinc pivalates is reported. The thioesters were prepared directly from the corresponding carboxylic acids under mild conditions, thus tolerating sensitive functional groups. Acylations of α-chiral S-pyridyl esters proceeded with very high stereoretention leading to optically enriched α-chiral ketones.
Photoinduced Dynamics of Bis-dipyrrinato-palladium(II) and Porphodimethenato-palladium(II) Complexes: Governing Near Infrared Phosphorescence by Structural Restriction
Riese, Stefan,Holzapfel, Marco,Schmiedel, Alexander,Gert, Ingo,Schmidt, David,Würthner, Frank,Lambert, Christoph
supporting information, p. 12480 - 12488 (2018/10/25)
Although superficially similar, the bis-dipyrrinato-palladium(II) complex 1 and the bridged porphodimethenato-palladium(II) complex 2 possess dramatically different structures in the ground state (proved by X-ray structure analysis) and in the singlet and