162147-95-7

Basic information

• Product Name: Ethanone, 2-chloro-1-(4-methoxyphenyl)-2-(phenylsulfinyl)-
• CAS NO: 162147-95-7
• Molecular Formula: C15H13ClO3S
• Molecular Weight: 308.785
• Mol File: 162147-95-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Ethanone, 2-chloro-1-(4-methoxyphenyl)-2-(phenylsulfinyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 2-chloro-1-(4-methoxyphenyl)-2-(phenylsulfinyl)-(162147-95-7)
• EPA Substance Registry System: Ethanone, 2-chloro-1-(4-methoxyphenyl)-2-(phenylsulfinyl)-(162147-95-7)

Safety Data

• Hazardous Substances Data: 162147-95-7(Hazardous Substances Data)

Upstream product

• 7205-94-9 chloromethyl phenyl sulfoxide 
• 121-98-2 methyl 4-methoxybenzoate 

Downstream Products

• 2196-99-8 2-chloro-1-(4-methoxyphenyl)ethanone 
• 52532-97-5 S-benzyl 2-(4-Methoxyphenyl)ethanethioate 
• 115348-15-7 N,N-diethyl-2-(4-methoxyphenyl)acetamide 
• 104-01-8 4-Methoxyphenylacetic acid 
• 23786-14-3 4-methoxy-phenyl acetic acid methyl ester 

Relevant articles and documents

Ligand exchange reaction of sulfoxides in organic synthesis: A new method for one-carbon homologation of esters to carboxylic acids and esters via α- chloro α-sulfinyl ketones

Reaction of the Carbanion of chloromethyl phenyl sulfoxide with esters gave α-chloro α-sulfinyl ketones, which were treated with KH followed by t- BuLi to afford one-carbon homologated acids and esters in good to excellent yields.