16222-22-3Relevant academic research and scientific papers
Novel oxidative α-tosyloxylation of alcohols with iodosylbenzene and p-toluenesulfonic acid and its synthetic use for direct preparation of heteroaromatics
Ueno, Makoto,Nabana, Takahiro,Togo, Hideo
, p. 6424 - 6426 (2003)
α-Tosyloxyketones and α-tosyloxyaldehydes were directly prepared from alcohols by treatment with iodosyl-benzene and p-toluenesulfonic acid monohydrate in good yields. This method can be used for the direct preparation of thiazoles, imidazoles, and imidaz
REGIOSPECIFIC CONVERSION OF TERMINAL ALKYNES TO KETOL PHOSPHATES WITH AN IODINE(III)-PHOSPHATE REAGENT
Koser, Gerald F.,Chen, Xiao,Chen, Kuanchiang,Sun, Guoping
, p. 779 - 782 (1993)
Terminal alkynes undergo regiospecific conversion to ketol phosphates when treated with the iodine(III)-phosphate 2 in acetonitrile containing water.
An efficient microwave-promoted solvent-free α-phosphoryloxylation of ketones
Pu, Ye,Fang, Yingguo,Yan, Jie
, p. 522 - 525 (2012/11/07)
An efficient solvent-free α-phosphoryloxylation of ketones under microwave irradiation is reported. When ketones reacted with phosphates and (diacetoxyiodo)benzene under microwave irradiation for short time, the α-phosphoryloxylaction of ketones was easil
An effective catalytic α-phosphoryloxylation of ketones with iodobenzene
Pu, Ye,Gao, Liumian,Liu, Huijun,Yan, Jie
experimental part, p. 99 - 103 (2012/03/26)
An effective catalytic method for α-phosphoryloxylation of ketones is reported. When ketones were reacted with phosphates in the presence of iodobenzene as the recyclable catalyst and m-chloroperbenzoic acid as the terminal oxidant in acetonitrile at room temperature, the α- phosphoryloxylation of ketones took place easily and the corresponding keto phosphates were obtained in moderate to good yields. Georg Thieme Verlag Stuttgart. New York.
Reactivities of novel [hydroxy(tosyloxy)iodo]arenes and [hydroxy(phosphoryloxy)iodo]arenes for α-tosyloxylation and α-phosphoryloxylation of ketones
Nabana, Takahiro,Togo, Hideo
, p. 4362 - 4365 (2007/10/03)
Novel [hydroxy(tosyloxy)iodo]arenes bearing 2-thienyl, 3-thienyl, N-tosyl-4-pyrazolyl, 3-trifluoromethylphenyl, and 3,5-bis(trifiuoromethy)phenyl as an aromatic group, and [hydroxy(phosphoryloxy)iodo]arenes bearing N. tosyl-4-pyrazolyl, 3-trifluoromethylp
