162382-36-7Relevant academic research and scientific papers
Strong evidence for a transient phosphinidenoid complex
Oezbolat, Aysel,Von Frantzius, Gerd,Perez, Janaina Marinas,Nieger, Martin,Streubel, Rainer
, p. 9327 - 9330 (2007)
(Figure Presented) Caught in the trap: Two different routes to the thermally unstable phosphinidenoid complex I are described, and chemical evidence for this novel intermediate is provided through selective reactions. For example, methyl iodide, dimethylcyanamide, or butyraldehyde furnished complexes II, III, and IV (see scheme) under very mild conditions.
Facile synthesis of pentacarbonyltungsten(0) complexes with oxaphosphirane ligands
Streubel, Rainer,Bode, Maren,Perez, Janaina Marinas,Schnakenburg, Gregor,Daniels, Joerg,Nieger, Martin,Jones, Peter G.
, p. 1163 - 1171 (2009/12/26)
Facile synthesis of tungsten(O) complexes of the type [{(R 1PCH(R2)-O)}W(CO)5] 7a-g (R1 = C5Me5) and. 8a - g (R1 = CH(SiMe 3)2) using transient Li/Cl phosph
