1624-46-0

Basic information

• Product Name: Benzenamine, 4-methoxy-N-[(4-methoxyphenyl)methylene]-, (E)-
• Synonyms: (4-methoxyphenyl)-[1-(4-methoxyphenyl)meth-(E)-ylidene]amine;(E)‐N,1‐bis(4‐methoxyphenyl)methanimine;(E)-4-methoxy-N-(4-methoxybenzylidene)aniline;(E)-N,1-bis-(4-methoxyphenyl)methanimine;N-(4-methoxybenzylidene)-4-methoxyaniline
• CAS NO: 1624-46-0
• Molecular Formula: C15H15NO2
• Molecular Weight: 241.29
• Mol File: 1624-46-0.mol
• Article Data: 23

Chemical Properties

• CAS DataBase Reference: Benzenamine, 4-methoxy-N-[(4-methoxyphenyl)methylene]-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine, 4-methoxy-N-[(4-methoxyphenyl)methylene]-, (E)-(1624-46-0)
• EPA Substance Registry System: Benzenamine, 4-methoxy-N-[(4-methoxyphenyl)methylene]-, (E)-(1624-46-0)

Safety Data

• Hazardous Substances Data: 1624-46-0(Hazardous Substances Data)

Upstream product

• 100-17-4 para-methoxynitrobenzene 
• 104-94-9 4-methoxy-aniline 
• 105-13-5 4-Methoxybenzyl alcohol 
• 100929-33-7 2-amino-2-(p-methoxyphemyl)ethanol 
• 3585-93-1 p-methoxydiphenylnitrone 
• 123-11-5 4-methoxy-benzaldehyde 
• 56644-00-9 (E)-N-cyclohexyl-1-(4-methoxyphenyl)methanimine 

Downstream Products

• 148260-85-9 (3S,4S)-1,4-bis(4-methoxyphenyl)-3-(3-phenylpropyl)-2-azetidinone 
• 130697-53-9 (3S,4R)-3-Amino-1,4-bis-(4-methoxy-phenyl)-azetidin-2-one 
• 130632-14-3 (3R,4R)-3-Amino-1,4-bis-(4-methoxy-phenyl)-azetidin-2-one 
• 133702-04-2 3-(4-Methoxy-phenyl)-2-[(E)-2-(4-methoxy-phenyl)-vinyl]-3H-benzo[g]quinazolin-4-one 
• 14429-14-2 N-(4-methoxybenzyl)-4-methoxyaniline 

Relevant articles and documents

Organoborane reagents in the C-alkylation of aromatic aldimines

The reaction of an aldimine with dicyclohexylboron chloride in the presence of hydrogen peroxide gives N-[cyclohexyl(aryl)methyl]arylamines 2 in good yields via oxidized imine-borane complexes. The amines can also be obtained by a three-component reaction

Catalytic Asymmetric γ-Lactam Synthesis from Enolisable Anhydrides and Imines

An anion-binding approach to the problem of preparing enantioenriched γ-lactams from enolisable anhydrides and imines is reported. A simple bisurea catalyst promotes the cycloaddition between α-aryl succinic anhydrides and either PMP- or benzhydryl-protec

Phosphine-Free Well-Defined Mn(I) Complex-Catalyzed Synthesis of Amine, Imine, and 2,3-Dihydro-1 H-perimidine via Hydrogen Autotransfer or Acceptorless Dehydrogenative Coupling of Amine and Alcohol

The application of nontoxic, earth-abundant transition metals in place of costly noble metals is a paramount goal in catalysis and is especially interesting if the air- and moisture-stable ligand scaffold is used. Herein, we report the synthesis of amines/imines directly from alcohol and amines via hydrogen autotransfer or acceptorless dehydrogenation catalyzed by well-defined phosphine-free Mn complexes. Both imines and amines can be obtained from the same set of alcohols and amines using the same catalyst, only by tuning the reaction conditions. The amount and nature of the base are found to be a highly important aspect for the observed selectivity. Both the primary and secondary amines have been employed as substrates for the N-alkylation reaction. As a highlight, we showed the chemoselective synthesis of resveratrol derivatives. Furthermore, the Mn-catalyzed dehydrogenative synthesis of structurally important 2,3-dihydro-1H-perimidines has also been demonstrated. Density functional theory calculations were also carried out to model the reaction path and to calculate the reaction profile.