162458-86-8

Basic information

• Product Name: cis-1-(p-anisyl)-3'R-(4,6-diacetoxy-2,3-enyl-α-O-glycoside)-4S-phenyl-azetidin-2-one
• Synonyms: cis-1-(p-anisyl)-3'R-(4,6-diacetoxy-2,3-enyl-α-O-glycoside)-4S-phenyl-azetidin-2-one
• CAS NO: 162458-86-8
• Molecular Weight: 481.502
• Mol File: 162458-86-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: cis-1-(p-anisyl)-3'R-(4,6-diacetoxy-2,3-enyl-α-O-glycoside)-4S-phenyl-azetidin-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: cis-1-(p-anisyl)-3'R-(4,6-diacetoxy-2,3-enyl-α-O-glycoside)-4S-phenyl-azetidin-2-one(162458-86-8)
• EPA Substance Registry System: cis-1-(p-anisyl)-3'R-(4,6-diacetoxy-2,3-enyl-α-O-glycoside)-4S-phenyl-azetidin-2-one(162458-86-8)

Safety Data

• Hazardous Substances Data: 162458-86-8(Hazardous Substances Data)

Upstream product

• 783-08-4 [4-(benzylideneamino)phenyl]methanol 
• 131968-76-8 (+/-)-(3R,4S)-3-acetoxy-N-(4-methoxyphenyl)-4-phenylazetidin-2-one 
• 101067-78-1 (+/-)-(3R,4S)-3-hydroxy-4-phenyl-N-(4-methoxyphenyl)azetidin-2-one 
• 2873-29-2 D-glucal triacetate 

Downstream Products

• 146924-94-9 (3R,4S)-(+)-3-hydroxy-1-(4-methoxyphenyl)-4-phenyl-2-azetidinone 
• 146924-90-5 (+)-cis-(3R,4S)-3-acetoxy-1-(4-methoxyphenyl)-4-phenyl-2-azetidinone 

Relevant articles and documents

Stereospecific Glycosylation via Ferrier Rearrangement for Optical Resolution

Diastereospecific glycosylation of racemic alcohols by reaction with suitable glycal derivatives in the presence of iodine provides easy access to both enantiomers as illustrated by the preparation of an optically pure α-hydroxy β-lactam that is an intermediate for the semisynthesis of taxol.