162608-99-3

Upstream product

• 125444-10-2 {2,4,6-tris-(bis-(trimethylsilyl)methyl)phenyl}lithium 
• 14044-65-6 borane-THF 
• 185910-20-7 2,4,6-tris[bis(trimethylsilyl)methyl]phenyl(mesityl)SiCN(2,4,6-triisopropylphenyl) 
• 115134-77-5 2,4,6-tris(bis(trimethylsilyl)methyl)benzene 
• 115160-05-9 1-bromo-2,4,6-tris[bis(trimethylsilyl)methyl]benzene 

Downstream Products

• 160359-04-6 (2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)(2,4,6-triisopropylphenyl)thioxosilane 
• 160359-06-8 5-(2,4,6-Triisopropyl-phenyl)-5-[2,4,6-tris-(bis-trimethylsilanyl-methyl)-phenyl]-[1,2,3,4,5]tetrathiasilolane 
• 160359-05-7 (2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)(dibromo)(2,4,6-triisopropylphenyl)silane 
• 473439-25-7 1-bromo-1-{2,4,6-tris[bis(trimethylsilyl)methyl]phenyl}-1,4-dihydro-1-silanaphthalene 
• 473439-22-4 1-{2,4,6-tris[bis(trimethylsilyl)methyl]phenyl}-1-silanaphthalene 
• 473439-24-6 1-{2,4,6-tris[bis(trimethylsilyl)methyl]phenyl}-1,4-dihydro-1-silanaphthalene 
• 262371-08-4 1-{2,4,6-tris[bis(trimethylsilyl)methyl]phenyl}-1,1-dihydro-1-silacyclohexa-2,4-diene 
• 215877-73-9 (2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)(2,4,6-triisopropylphenyl)silane 

Relevant academic research and scientific papers

Reaction of stable silylene-isocyanide complexes with boranes: Synthesis and properties of the first stable silylborane-isocyanide complexes

Stable silylene-isocyanide complexes [Tbt(Mes)SiCNAr (Ar = Tbt, Mes*; Tbt = 2,4,6-tris[bis(trimethylsilyl)methyl]phenyl; Mes = mesityl; Mes* = 2,4,6-tri-t-butylphenyl)] reacted with BH3·THF to give the first stable silylborane-isocyanide complexes [Tbt(MeS)SiHBH2CNAr]. The thermal equilibrium between Tbt(Mes)SiHBH2CNAr and TbtSiH2BH(Mes)CNAr was observed.

An unexpected elimination of cyclopentadienide anion in the reaction of silacyclohexadienes with a bulky aryllithium

The reaction of silacyclohexadienes with an extremely hindered aryllithium, TbtLi (Tbt = 2,4,6-tris[bis(trimethylsilyl)-methyl]phenyl), gave no expected Tbt-substituted silacyclohexadienes but trihydrosilane, TbtSiH3, via the elimination of cyc

SYNTHESIS AND REACTIONS OF NOVEL ORGANOSULFUR COMPOUNDS HAVING A HIGHLY STERICALLY BULKY GROUP, 2,4,6-TRISPHENYL

Novel cyclic metallatetrasulfides containing Group 14 metals have been synthesized by the thermal reactions of the corresponding metal hydrides substituted by the title new steric protection group.The structure of newly obtained metallacyclopolysulfides is of great interest in comparison with that of the previously reported di-?-cyclopentadienylmetal pentasulfides of titanium(IV) and vanadium(IV).Attempts to prepare the metal-sulfur double bond compounds from the metallacyclopolysulfides are also described.