262371-08-4Relevant academic research and scientific papers
The chemistry of stable silabenzenes
Tokitoh, Norihiro,Wakita, Keiji,Matsumoto, Takeshi,Sasamori, Takahiro,Okazaki, Renji,Takagi, Nozomi,Kimura, Masahiro,Nagase, Shigeru
experimental part, p. 487 - 507 (2009/12/01)
Stable silabenzenes (1a; R = Tbt, 1b; R = Bbt) were synthesized by taking advantage of extremely bulky and efficient steric protection groups, 2,4,6-tris[bis(trimethylsilyl)methyl]phenyl (Tbt) and 2,6-bis- [bis(trimethylsilyl)methyl]-4-[tris(trimethylsily
Synthesis and properties of an over-crowded Silabenzene stable at ambient temperature
Wakita, Keiji,Tokitoh, Norihiro,Okazaki, Renji,Nagase, Shigeru
, p. 634 - 636 (2007/10/03)
Solid-state, room-temperature stability for silabenzene 1 is granted by the bulky silane rendering kinetic inertness. Silabenzene 1 is synthesized in good yield from the crowded chlorosilane 2 with tert-butyllithium. The delocalized, aromatic nature of 1
