162613-15-2

Upstream product

• 196704-04-8 3,4-di-O-benzyl-6-O-triisoporpylsilyl-S-thiaethyl-β-D-glucopyranose 
• 1356163-67-1 3,4-bis-O-benzyl-6-triisoporpylsilyl-1,2-O-(1-methoxyethylidene)-α-D-glucopyranose 
• 75-08-1 ethanethiol 
• 141810-60-8 ethyl 3-O-benzyl-4,6-O-benzylidene-1-thio-β-D-glucopyranoside 
• 162681-47-2 ethyl 2-O-acetyl-3-O-benzyl-4,6-O-benzylidene-1-thio-β-D-glucopyranoside 

Downstream Products

• 1055032-87-5 Acetic acid (2S,3R,4S,5S,6S)-4,5-bis-benzyloxy-2-ethylsulfanyl-6-formyl-tetrahydro-pyran-3-yl ester 
• 162613-17-4 Methyl (ethyl 3,4-di-O-benzyl-1-thio-β-D-glucopyranosid)uronate 
• 162613-16-3 Methyl (ethyl 2-O-acetyl-3,4-di-O-benzyl-1-thio-β-D-glucopyranosid)uronate 
• 162613-20-9 Methyl (ethyl 3,4-di-O-benzyl-2-O-pivaloyl-1-thio-β-D-glucopyranosid)uronate 
• 162613-18-5 Methyl (ethyl 2-O-benzoyl-3,4-di-O-benzyl-1-thio-β-D-glucopyranosid)uronate 
• 162613-19-6 Methyl (ethyl 3,4-di-O-benzyl-2-O-(p-methoxybenzoyl)-1-thio-β-D-glucopyranosid)uronate 
• 1053632-38-4 (2S,3S,4S,5R,6R)-3,4-Bis-benzyloxy-6-((2R,4aR,6S,7S,8S,8aR)-8-benzyloxy-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yloxy)-5-(2,2-dimethyl-propionyloxy)-tetrahydro-pyran-2-carboxylic acid methyl ester 

Relevant academic research and scientific papers

First total synthesis of ganglioside DSG-A possessing neuritogenic activity

The first total synthesis of ganglioside DSG-A (1) is achieved via chemoselective glycosylation and a [1 + 1 + 2] synthetic strategy. We have also developed an efficient method that can be handled on large scale (50 g) for the synthesis of the phytosphingosine. This journal is

Synthesis of Methyl (Ethyl 2-O-acyl-3,4-di-O-benzyl-1-thio-β-D-glucopyranosid)uronates and Evaluation of Their Use as Reactive β-Selective Glucuronic Acid Donors

The synthesis of derivatives of methyl (ethyl 2-O-acyl-3,4-di-O-benzyl-1-thio-β-D-glucopyranosid)uronate with different ester groups (acetyl, benzoyl, pivaloyl, and anisoyl) at O-2 is described.The synthesis proceeds via a two-step oxidation (DMSO/DCC fol