16269-27-5

Upstream product

• 2235-15-6 1(2H)-acenaphthylenone 
• 208-96-8 acenaphthylene 
• 82-86-0 acenaphthene quinone 
• 17976-92-0 1,2-dihydroacenaphthylene-1,2-diol 
• 13152-85-7 2,2-Dichlor-1(2H)-acenaphthenon 

Downstream Products

• 55868-14-9 8-benzyl-acenaphtho[1,2-d]thiazole 
• 82-86-0 acenaphthene quinone 
• 518-05-8 Naphthalene-1,8-dicarboxylic acid 
• 13286-14-1 [1,1']biacenaphthylenylidene-2,2'-dione 

Relevant academic research and scientific papers

A Convenient One-Pot Synthesis of Acenaphthenequinones from 1-Acenaphthenones by NBS-DMSO Oxidation

Acenaphthenequinone was obtained in 95percent yield whwn the teaction of 1-acenaphthenone with N-bromosuccinimide was carried uot in dimethyl sulfoxide at room temperature.Under similar conditions, several acenaphthenequinones were prepared from the corresponding 1-acenaphthenones in good yield.

Visibly Emitting Thiazolyl-Uridine Analogues as Promising Fluorescent Probes

Microenvironment-sensitive fluorescent (ESF) nucleosides are powerful tools for nucleic acid research. The new 5-substituted uridine analogues are synthesized, which comprise a 4H-cyclopenta[d]thiazole ring obtained by the Hantzsch synthesis reaction of 5-thioamide-uridine with aromatic α-bromocarbonyl compounds. The emission maximum of new compounds is in the visible region. They exhibit strong solvent- A nd pH-dependent fluorescent properties, indicating their promising ability to be fluorescent probes.

Palladium-catalyzed trimerization of strained cycloalkynes: Synthesis of decacyclene

Palladium-catalyzed cyclotrimerization was applied to three strained cycloalkynes. Pd(PPh3)4 and Pt(PPh3)4-catalyzed cyclotrimerizations of cyclohexyne (2) afforded dodecahydrotriphenylene (3) in 64% and 62% yields, respectively, but subjecting cyclopentyne to the same conditions failed to afford isolable amounts of the cyclotrimer. Finally, decacyclene (15), a putative C60-fullerene precursor, was obtained in 23% yield by Pd2(dba)3-catalyzed cyclotrimerization of acenaphthyne (14).