1627150-24-6

Basic information

• Product Name: C₁₃H₁₅NO₃
• CAS NO: 1627150-24-6
• Molecular Weight: 233.267
• Mol File: 1627150-24-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₃H₁₅NO₃(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₃H₁₅NO₃(1627150-24-6)
• EPA Substance Registry System: C₁₃H₁₅NO₃(1627150-24-6)

Safety Data

• Hazardous Substances Data: 1627150-24-6(Hazardous Substances Data)

Upstream product

• 2960-66-9 4-oxo-but-2-enoic acid ethyl ester 
• 119930-77-7 O-o-Tolyl-hydroxylamine; hydrochloride 

Downstream Products

• 1627150-08-6 (2E,4E)-4-[(2-methylphenoxy)imino]-2-butenoic acid 2,3,4,5,6-pentafluorophenyl ester 

Relevant articles and documents

Direct synthesis of benzofuro[2,3-b]pyrroles through a radical addition/[3,3]-sigmatropic rearrangement/cyclization/lactamization cascade

A straightforward synthetic method for the construction of benzofuro[2,3-b]pyrrol-2-ones by a novel domino reaction through a radical addition/[3,3]-sigmatropic rearrangement/cyclization/lactamization cascade has been developed. The domino reaction of O-phenyl-conjugated oxime ether with an alkyl radical allows the construction of two heterocycles with three stereogenic centers as a result of the formation of two C-C bonds, a C-O bond, and a C-N bond in a single operation, leading to pyrrolidine-fused dihydrobenzofurans, which are not easily accessible by existing synthetic methods. Furthermore, asymmetric synthesis of benzofuro[2,3-b]pyrrol-2-one derivatives through a diastereoselective radical addition reaction to a chiral oxime ether was also developed.