1627210-82-5Relevant articles and documents
Palladium(II)-Catalyzed Reductive Cyclization of N-Tosyl-Tethered 1,7-Enynes: Enantioselective Synthesis of 1,2,3,4-Tetrahydroquinolines
Chen, Junjie,Han, Xiuling,Lu, Xiyan
, p. 8153 - 8157 (2019)
A novel Pd(II)-catalyzed reductive asymmetric cyclization of N-tosyl-tethered 1,7-enynes using ethanol as a hydrogen source is reported. This reaction provides facile ways for the synthesis of two types of 1,2,3,4-tetrahydroquinolines possessing a chiral
Intramolecular aminocyanation of alkenes by N-CN bond cleavage
Pan, Zhongda,Pound, Sarah M.,Rondla, Naveen R.,Douglas, Christopher J.
, p. 5170 - 5174 (2014/05/20)
A metal-free, Lewis acid promoted intramolecular aminocyanation of alkenes was developed. B(C6F5)3 activates N-sulfonyl cyanamides, thus leading to a formal cleavage of the N-CN bonds in conjunction with vicinal addition o