52562-19-3

Basic information

• Product Name: 2-ISOPROPENYLANILINE
• Synonyms: 2-(1-methylethenyl)-benzenamin;o-Isopropenylaniline;2-ISOPROPENYLANILINE;2-ISOPROPENYLANILINE, 98+%;2-Isopropenylaniline, GC 98+%;2-(1-Methylethenyl)benzenamine;2-(1-Methylvinyl)aniline;2-(1-Propene-2-yl)benzeneamine
• CAS NO: 52562-19-3
• Molecular Formula: C₉H₁₁N
• Molecular Weight: 133.19
• EINECS: 258-008-7
• Product Categories: Monomers;Polymer Science;Styrene and Functionalized Styrene Monomers
• Mol File: 52562-19-3.mol
• Article Data: 51

Chemical Properties

• Boiling Point: 95 °C13 mm Hg(lit.)
• Flash Point: 173 °F
• Appearance: /
• Density: 0.978 g/mL at 25 °C(lit.)
• Vapor Pressure: 0.173mmHg at 25°C
• Refractive Index: n20/D 1.57(lit.)
• Storage Temp.: Keep in dark place,Sealed in dry,Room Temperature
• PKA: 3?+-.0.10(Predicted)
• BRN: 3081217
• CAS DataBase Reference: 2-ISOPROPENYLANILINE(CAS DataBase Reference)
• NIST Chemistry Reference: 2-ISOPROPENYLANILINE(52562-19-3)
• EPA Substance Registry System: 2-ISOPROPENYLANILINE(52562-19-3)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36
• WGK Germany: 3
• Hazardous Substances Data: 52562-19-3(Hazardous Substances Data)

Usage

Chemical Properties

CLEAR SLIGHTLY YELLOW LIQUID

InChI:InChI=1/C9H11N/c1-7(2)8-5-3-4-6-9(8)10/h3-6H,1,10H2,2H3

Upstream product

• 120780-16-7 4-Methyl-2-p-tolyl-2λ⁴-benzo[c][1,2]thiazine 2-oxide 
• 120780-15-6 4-Methyl-2-p-tolyl-3-trimethylsilanyl-2λ⁴-benzo[c][1,2]thiazine 2-oxide 
• 15833-00-8 o-aminophenyldimethylcarbinol 
• 75-16-1 methylmagnesium bromide 
• 551-93-9 2-aminoacetophenone 
• 60249-97-0 1-(1-methylethenyl)-2-nitrobenzene 
• 74-83-9 methyl bromide 
• 552-89-6 2-nitro-benzaldehyde 
• 615-36-1 2-bromoaniline 
• 1885-29-6 anthranilic acid nitrile 
• 2065-66-9 methyl-triphenylphosphonium iodide 
• 490035-95-5 N-benzyl-2-(prop-1-en-2-yl)benzen-amine 
• 62-53-3 aniline 
• 74-99-7 prop-1-yne 

Downstream Products

• 119449-53-5 N-(2-(prop-1-en-2-yl)phenyl)furan-2-carboxamide 
• 119449-51-3 N-(2-Isopropenyl-phenyl)-propionamide 
• 81051-11-8 o-isopropenyl-N,N-dibenzylaniline 
• 148336-12-3 4-methoxy-N-(2-(prop-1-en-2-yl)phenyl)benzamide 
• 119449-52-4 Hexanoic acid (2-isopropenyl-phenyl)-amide 
• 88884-37-1 N-benzoyl-N'-2-isopropenylphenylthiourea 
• 101530-90-9 5-Benzyl-3,6-dihydro-6-oxo-1,3-diphenyl-1-pyrimidinium-4-olat 
• 112794-56-6 5-Benzyl-3,6-dihydro-1-(2-isopropenylphenyl)-6-oxo-3-phenyl-1-pyrimidinium-4-olat 
• 96807-23-7 3,6-Dihydro-5-methyl-6-oxo-1,3-diphenyl-1-pyrimidinium-4-olat 
• 112794-53-3 3,6-Dihydro-1-(2-isopropenylphenyl)-5-methyl-6-oxo-3-phenyl-1-pyrimidinium-4-olat 
• 864131-95-3 N,N'-diphenylformamidine 
• 112794-52-2 N¹-(2-Isopropenylphenyl)-N²-phenylformamidin 
• 106012-42-4 2-phenyl-N-(2-(prop-1-en-2-yl)phenyl)acetamide 
• 19155-24-9 3,3-dimethyloxindole 

Relevant articles and documents

Trifluoromethylthio-containing tryptamine derivative and preparation thereof, and application in prevention and treatment of plant viruses and pathogenic bacteria

The invention relates to a trifluoromethylthio-containing tryptamine derivative I and a preparation method thereof, and application of the trifluoromethylthio-containing tryptamine derivative I in prevention and treatment of plant viruses and pathogenic bacteria. According to the invention, the trifluoromethylthio-containing tryptamine derivative I shows anti-plant virus activity, wherein the inhibition rate of the derivative containing chlorine atoms in the structure on tobacco mosaic virus (TMV) can reach the level equivalent to that of virazole; and the compound also shows certain anti-plant pathogenic bacterium activity, and has relatively good inhibitory activity on physalospora piricola.

Self-catalyzed phototandem perfluoroalkylation/cyclization of unactivated alkenes: Synthesis of perfluoroalkyl-substituted quinazolinones

A novel visible-light-induced radical tandem trifluoromethylation/cyclization of unactivated alkenes with sodium perfluoroalkanesulfinates (Rf = CF3, C3F7, C4F9, C6F13, C8F17) under air atmosphere has been developed. A range of quinazolinones containing unactivated alkene moiety and sodium perfluoroalkanesulfinates were compatible with this transformation, leading to a variety of perfluoroalkyl-substituted quinazoline alkaloids. Remarkably, the experiment can be carried out without any metal catalyst, strong oxidant, or external photosensitizer.

Electrochemical oxidative radical cascade cyclization of olefinic amides and thiophenols towards the synthesis of sulfurated benzoxazines, oxazolines and iminoisobenzofurans

Heterocycles containing N and O are important structures in pharmaceuticals, agrochemicals and functional molecules. The synthesis of these compounds usually requires complex substrates and harsh reaction conditions. Herein, we introduce a mild and efficient electrochemical oxidative strategy to construct benzoxazines, oxazolines and iminoisobenzofurans without the requirement of a transition-metal catalyst and an external oxidant. In a simple undivided cell, various olefinic amides and thiophenols/diselenides react to generate 69 examples of thiolation and selenylation heterocycles in up to 83% yields. Furthermore, this radical cascade reaction provided a facile method for constructing C-S/C-Se and C-O bonds in one step.