16274-87-6Relevant academic research and scientific papers
Asymmetric microbial conversion of (E)-2-benzylideneindan-1-one by the filamentous fungi Botrytis cinerea, Trichoderma viride, and Eutypa lata
Pinedo-Rivilla, Cristina,Aleu, Josefina,Collado, Isidro G.
experimental part, p. 1653 - 1657 (2012/01/30)
The transformation of (E)-2-benzylideneindan-1-one 1 by the filamentous fungi Botrytis cinerea, Trichoderma viride, and Eutypa lata as biocatalysts was studied. The results showed the catalytic potential of these fungi in affording several hydroxylation a
Biocatalytic preparation and absolute configuration of enantiomerically pure fungistatic anti-2-benzylindane derivatives. Study of the detoxification mechanism by Botrytis cinerea
Pinedo-Rivilla, Cristina,Aleu, Josefina,Grande Benito, Manuel,Collado, Isidro G.
experimental part, p. 3784 - 3789 (2010/09/06)
Enantiomerically pure 2-benzylindane derivatives were prepared using biocatalytic methods and their absolute configuration determined. (1R,2S)-2-Benzylindan-1-ol ((1R,2S)-2) and (S)-2-benzylindan-1-one ((S)-3) were produced by fermenting baker's yeast. Li
On the baker's yeast mediated transformation of α-bromoenones. Synthesis of (1S,2R)-2-bromoindan-1-ol and (2s,3s)-3-bromo-4-phenylbutan-2- ol
Aleu, Josephina,Fronza, Giovanni,Fuganti, Claudio,Perozzo, Valentina,Serra, Stefano
, p. 1589 - 1596 (2007/10/03)
Fermenting baker's yeast converts α-bromo substituted enones 7 and 10 into enantiomerically pure (1S,2R)2-bromoindan-1-ol 3 and (2S,3S)-3-bromo-4- phenylbutan-2-ol 11, respectively, through the intermediacy of the corresponding saturated ketones. Structurally related 16 provides the (2R)- allylic alcohol 17 prevalently.
Hydroxy-Directed Hydroaluminations: A Stereoselective Approach to Cycloalkanols From β-Aryl Enones.
Koch, Kevin,Smitrovich, Jacqueline H.
, p. 1137 - 1140 (2007/10/02)
Various aryl substituted enones are reduced using lithium aluminum hydride to afford sterioselectively trans substituted alkanols.Mechanistic studies demonstrate 1,2-addition followed by hydroxy-directed hydroalumination of the conjugated styryl unit.
Undirectional Triple and Double Hydrogen Rearrangement Reactions in the Radical Cations of γ-Arylalkanols
Kuck, Dietmar,Filges, Ulrich
, p. 643 - 653 (2007/10/02)
A novel fragmentation reaction accompanied by the unidirectional migration of three hydrogen atom has been found in the radical cations of γ-arylpropanols with electron-donating substituents in the para position.This triple hydrogen (3H) rearrangement rea
Stereospecificity of Introduction of Hydride Ion during Double Bond Reduction of 2-Benzylidene-1-tetralone and Other Related Compounds
Chatterjee, Amareshwar,Dutta, Lakshmi N.,Chatterjee, Swapan K.
, p. 955 - 960 (2007/10/02)
Lithium aluminium hydride reduction of the benzylidene derivatives (1a-c) and (5) in refluxing THF is shown to be stereospecific, the saturated alcohol isolated in each case having the trans-stereochemistry.The benzyl ketones (30a, b, d) and (7) on sodium
