162754-74-7

Basic information

• Product Name: 1-methyl-1-<(Z)-2-phenylethenyl>silacyclobutane
• Synonyms: 1-methyl-1-<(Z)-2-phenylethenyl>silacyclobutane
• CAS NO: 162754-74-7
• Molecular Weight: 188.345
• Mol File: 162754-74-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-methyl-1-<(Z)-2-phenylethenyl>silacyclobutane(CAS DataBase Reference)
• NIST Chemistry Reference: 1-methyl-1-<(Z)-2-phenylethenyl>silacyclobutane(162754-74-7)
• EPA Substance Registry System: 1-methyl-1-<(Z)-2-phenylethenyl>silacyclobutane(162754-74-7)

Safety Data

• Hazardous Substances Data: 162754-74-7(Hazardous Substances Data)

Upstream product

• 536-74-3 phenylacetylene 
• 162754-70-3 1-methyl-1-(phenylethynyl)silacyclobutane 

Downstream Products

• 137472-39-0 1-<(Z)-1,2-epoxy-2-phenylethyl>-1-methylsilacyclobutane 
• 13159-16-5 (Z)-5-phenylpent-4-en-1-ol 
• 13159-16-5 (E)-5-phenyl-4-penten-1-ol 
• 137472-45-8 erythro-2-<1-hydroxy(phenyl)methyl>-1-isopropoxy-1-methylsilacyclopentane 
• 137472-41-4 erythro-2-hydroxyphenylmethyl-1,1-dimethyl-1-silacyclopentane 

Relevant articles and documents

Nucleophile-induced ring enlargement of 1-(1-iodoalkyl)silacyclobutane and 1-(1,2-epoxyalkyl)silacyclobutane into silacyclopentane. Application to the synthesis of 1,4-diol, 4-alken-1-ol, and 1,4,5-triol

Two methods for ring enlargement of silacyclobutane into silacyclopentane have been described. (1) Treatment of 1-(1-iodoalkyl)silacyclobutane with t-BuOK or AgOAc provided 2-alkyl-1-silacyclopentanes which were easily converted into 1,4-diols by oxidativ