137472-45-8

Basic information

• Product Name: erythro-2-<1-hydroxy(phenyl)methyl>-1-isopropoxy-1-methylsilacyclopentane
• Synonyms: erythro-2-<1-hydroxy(phenyl)methyl>-1-isopropoxy-1-methylsilacyclopentane
• CAS NO: 137472-45-8
• Molecular Weight: 264.44
• Mol File: 137472-45-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: erythro-2-<1-hydroxy(phenyl)methyl>-1-isopropoxy-1-methylsilacyclopentane(CAS DataBase Reference)
• NIST Chemistry Reference: erythro-2-<1-hydroxy(phenyl)methyl>-1-isopropoxy-1-methylsilacyclopentane(137472-45-8)
• EPA Substance Registry System: erythro-2-<1-hydroxy(phenyl)methyl>-1-isopropoxy-1-methylsilacyclopentane(137472-45-8)

Safety Data

• Hazardous Substances Data: 137472-45-8(Hazardous Substances Data)

Upstream product

• 2388-10-5 lithium isopropoxide 
• 137472-39-0 1-<(Z)-1,2-epoxy-2-phenylethyl>-1-methylsilacyclobutane 
• 67-63-0 isopropyl alcohol 
• 162754-70-3 1-methyl-1-(phenylethynyl)silacyclobutane 
• 536-74-3 phenylacetylene 
• 162754-74-7 1-methyl-1-<(Z)-2-phenylethenyl>silacyclobutane 
• 4440-01-1 lithium phenylacetylide 

Downstream Products

• 13159-16-5 (E)-5-phenyl-4-penten-1-ol 
• 13159-16-5 (Z)-5-phenylpent-4-en-1-ol 
• 32346-57-9 erythro-1-phenyl-1,2,5-pentanetriol 

Relevant articles and documents

Nucleophile-induced ring enlargement of 1-(1-iodoalkyl)silacyclobutane and 1-(1,2-epoxyalkyl)silacyclobutane into silacyclopentane. Application to the synthesis of 1,4-diol, 4-alken-1-ol, and 1,4,5-triol

Two methods for ring enlargement of silacyclobutane into silacyclopentane have been described. (1) Treatment of 1-(1-iodoalkyl)silacyclobutane with t-BuOK or AgOAc provided 2-alkyl-1-silacyclopentanes which were easily converted into 1,4-diols by oxidativ